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T104 low base synthetic alkyl benzene calcium sulfonate

T104 Low Base Synthetic Alkyl Benzene Calcium Sulfonate is a detergent additive commonly used in lubricants, engine oils, and industrial oils. It is a calcium sulfonate based on a synthetic alkyl benzene sulfonic acid, neutralized with calcium to form a low-base number (TBN) salt.


🔬 Chemical Overview:

  • Type: Calcium sulfonate (low-base type)
  • Source: Synthetic alkyl benzene sulfonic acid
  • TBN (Total Base Number): Typically around 20–40 mg KOH/g
  • Appearance: Amber to brown viscous liquid
  • Solubility: Oil-soluble

⚙️ Key Functions in Lubricant Formulations:

FunctionDescription
DetergencyKeeps metal surfaces clean by dispersing contaminants
Rust inhibitionProvides corrosion protection for ferrous metals
Acid neutralizationOffers mild neutralization of acidic byproducts
Thermal stabilityPerforms well under high-temperature operating conditions

🔧 Low Base vs High Base:

PropertyLow Base (T104)High Base (e.g., TBN 250)
TBN~20–40 mg KOH/g>200 mg KOH/g
Main RoleDetergency, rust preventionStrong acid neutralization, detergency
Ash ContentLowerHigher (may affect emissions/additive limits)
Typical Use Rate~0.5–3.0%Up to 5% depending on formulation

🛢️ Applications:

  • Engine oils (diesel and gasoline)
  • Hydraulic oils
  • Gear oils
  • Compressor oils
  • Rust-preventive oils

Often used in combination with:

  • ZDDPs (antiwear/antioxidant)
  • Dispersants (PIB succinimides)
  • Antioxidants (amines, phenols)

📌 Advantages of T104 Type:

  • Lower ash content, helpful for low-SAPS (sulfated ash, phosphorus, sulfur) formulations
  • Synthetic alkyl benzene base offers better solubility and thermal stability than natural petroleum sulfonates
  • Improves rust protection especially in the presence of water

🏭 Formulation Tip:

If you’re designing a low-ash or mid-SAPS engine oil, a low base calcium sulfonate like T104 is a good choice to balance rust protection and cleanliness without adding too much base reserve or ash.


Would you like a sample using T104, or help comparing it with high-base or natural sulfonates?

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1.What is the calcium alkyl benzene sulfonate?

Calcium alkyl benzene sulfonate is a type of synthetic detergent that is commonly used as an active ingredient in various household and industrial cleaning products, including laundry detergents, dishwashing detergents, and general-purpose cleaners. It is a surfactant, which means it has both hydrophilic (water-attracting) and hydrophobic (water-repelling) components, allowing it to effectively remove dirt, grease, and stains from surfaces.

The structure of calcium alkyl benzene sulfonate consists of a hydrophilic sulfate group (SO4) and a hydrophobic alkyl benzene tail. The calcium ion (Ca2+) is associated with the sulfate group, and it helps to improve the stability and solubility of the detergent in water.

This type of detergent is known for its excellent cleaning and foaming properties. It can emulsify and suspend dirt and grease in water, allowing them to be easily rinsed away. Calcium alkyl benzene sulfonate is also relatively mild on the skin and is considered environmentally friendly compared to some older formulations of detergents.

2.What is calcium alkyl benzene sulfonate used for?

Calcium alkyl benzene sulfonate is often used as a detergent and surfactant in various applications. Surfactants are compounds that have both hydrophilic (water-attracting) and hydrophobic (water-repelling) parts in their molecular structure. This dual nature allows them to lower the surface tension of liquids, enabling them to mix with substances that wouldn’t normally dissolve in the liquid.

3.Calcium alkyl benzene sulfonate, being a type of surfactant, is commonly used in:

①Household Cleaning Products

It can be found in laundry detergents, dishwashing detergents, and various multipurpose cleaners. The surfactant properties of calcium alkyl benzene sulfonate help break down and remove dirt, grease, and stains from various surfaces.

②Industrial Cleaners

It is used in industrial settings for cleaning equipment, machinery, and surfaces. Its ability to emulsify oils and solubilize various substances makes it effective in heavy-duty cleaning applications.

③Personal Care Products

Calcium alkyl benzene sulfonate can be found in personal care products such as shampoos, body washes, and soaps. In these products, it acts as a foaming agent and helps improve the dispersion of oils and dirt on the skin and hair.

④Agricultural Formulations

Some agricultural formulations, like pesticides and herbicides, can use calcium alkyl benzene sulfonate as a dispersing agent to ensure that the active ingredients are evenly distributed when mixed with water or other liquids.

⑤Emulsifiers


This compound can also be used as an emulsifier in various applications, such as in the production of emulsified products like paints, coatings, and food products.

4.What is worth noting about using alkyl benzene calcium sulfonate?

It’s worth noting that while calcium alkyl benzene sulfonate has various industrial applications, its use in consumer products has raised some environmental and health concerns due to its persistence in the environment and potential effects on aquatic life. As a result, there has been ongoing research and regulatory scrutiny surrounding the use of this compound and similar surfactants in products. Always refer to product labels and safety data sheets for information about the ingredients in specific products.

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5.T104 low base synthetic alkyl benzene calcium sulfonate

The synthetic calcium sulfonate with low base number is one of the series of petroleum additives developed by us. It’s mainly made from Long-Chain Linear Alkyl Benzene Sulfonate.As a major metal detergent, this product has excellent dispersancy, good anti-rust property and high-temperature detergency, so it is widely used for different engine oil.
①Excellent detergency
②Excellent water separation property and anti-foam performance
③Low turbidity and good compatibility with various kinds of base oils

6.Welcome to contact us

Shanghai Minglan Chemical Co.,Ltd. is a professional manufacturer and supplier of lubricant additives.We have committed to supply the professional,perfect, effective and satisfactory lubrication solutions all the time. Our lubricant additive packages meet the specification requirement of bunch test,and possess excellent product performance and reliable quality,so that always holds technology leading status in the lubrication industry.We are specialized in supplying high-quality lubricant additive products with nearly 20 years of experience. Such as detergent、ashless dispersant、ZDDP、EP antiwear additive、antiodant、viscosity index improver、rust inhibitor、Pour Point Depressant、engine oil additive package、gear oil additive package、hydraulic oil additive package and so on.

If you are interested in the alkyl benzene calcium sulfonate, I recommend reaching out to us,we can provide more detailed information about our product offerings and may assist in selecting the most suitable oil detergent additive for your lubricant application.

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