Protective additives in lubricating oils are compounds added to the oil’s formula to enhance its performance and provide additional protection to the engine or machinery in which it is used. Some common protective additives in lubricants include:
- Anti-wear additives: These additives form a protective film on the metal surface to prevent metal-to-metal contact and reduce wear. Some common antiwear additives include zinc dialkyldithiophosphate (ZDDP) and molybdenum.
- Detergent: Detergent additives prevent the formation of deposits and sludge and help keep engines and machinery clean. They remove existing deposits and suspend them in the oil for removal by the oil filter. Some commonly used cleaners include calcium sulfonate and magnesium sulfonate.
- Dispersants: Dispersant additives are used to prevent the formation of sludge, varnish, and other harmful deposits by suspending insoluble contaminants in the oil. This allows them to be efficiently carried away and removed by the oil filter. Some common dispersant additives include polyisobutylene and succinimide.
- Defoamers: These additives are used to control the formation of foam in oils. Foam reduces the lubricating properties of the oil, leading to insufficient lubrication and increased wear. Defoaming agents help break down foam and improve overall lubrication efficiency. Silicones and polymethylsiloxanes are commonly used defoaming agents.
- Corrosion and rust inhibitors: These additives help protect metal surfaces from corrosion and rust caused by moisture, acids and other contaminants. They form a protective barrier on the metal surface, preventing corrosive substances from coming into direct contact with the metal. Some common corrosion and rust inhibitors include zinc compounds and organic amines.
- Extreme Pressure Additives: These additives provide additional protection by forming a lubricating film on metal surfaces under high load and extreme pressure conditions. They help minimize friction, reduce wear and prevent surface damage. Some common extreme pressure additives include sulfur compounds and chlorinated paraffins.
- Antioxidants: Antioxidant additives help prevent oxidation and degradation of oil by neutralizing and inhibiting the formation of harmful free radicals. This helps extend the life of the oil and maintain its performance under high temperature and oxidizing conditions. Some commonly used antioxidants include phenols and amines.
- Friction modifier: Friction modifier additives are used to reduce friction and improve fuel efficiency. They form a lubricating film on metal surfaces, reducing friction between metal surfaces and improving the overall efficiency of machinery. Molybdenum disulfide and graphite are commonly used friction modifiers.
- Pour point depressants: These additives lower the pour point of the oil, allowing it to flow at lower temperatures. They help prevent oil from becoming too thick or solidifying in cold conditions, ensuring proper lubrication even at low temperatures. Polymer and wax modifiers are commonly used pour point depressants.

These are just a few examples of the many protective additives used in lubricants. The specific formulation and combination of additives varies depending on the application requirements and the desired performance characteristics of the lubricant.

