news

What effect do extreme pressure additives have on lubricants?

Extreme Pressure (EP) additives play a critical role in enhancing the performance and protection of lubricants, especially under high load, high pressure, and boundary lubrication conditions — where conventional oil films break down. Here’s a detailed look at their effects on lubricants:


🛠️ 1. Increased Load-Carrying Capacity

EP additives form protective chemical films on metal surfaces, allowing the lubricant to withstand extremely high pressures without metal-to-metal contact.

Result:
✅ Prevents scuffing, seizure, and surface welding in gears, bearings, and heavily loaded contacts.


🔩 2. Reduced Wear and Surface Damage

When operating under boundary lubrication (thin or absent oil film), EP additives chemically react with metal surfaces (usually iron/steel) to form sacrificial layers that reduce friction and wear.

Common EP reactions:

  • Sulfur, phosphorus, or chlorine-containing EP additives react under heat to form metal sulfides or phosphates, which are softer than the metal and prevent direct contact.

Result:
✅ Longer equipment life
✅ Smoother surface finish
✅ Improved reliability


🔧 3. Improved Gear and Bearing Performance

In gearboxes (like automotive, industrial, or marine), EP additives prevent pitting, micro-welding, and gear scoring, especially in:

  • Hypoid gears
  • Spur and helical gears under high torque
  • Heavy-duty bearings

Result:
✅ Smooth operation under shock loads
✅ Higher torque transfer capability


🌡️ 4. Thermal Protection

EP additives activate at high temperatures (typically above 100–150 °C), forming protective films only when needed — reducing unnecessary chemical activity in normal conditions.

Result:
✅ Targeted protection
✅ Reduced additive depletion
✅ Thermal stability for long service life


🧪 5. Chemical Impact on Oil

While highly beneficial, EP additives can influence lubricant properties in some cases:

PropertyPotential Effect (if unbalanced)
Oxidation stabilitySulfur/phosphorus EP may increase oxidation risk
CorrosivityActive sulfur types can corrode yellow metals (e.g., copper, brass)
CompatibilityCertain EP types may attack seals or soft materials
Ash contentSome EPs increase sulfate ash in engine or gear oils

✅ Mitigation: Use of buffered or non-corrosive EP agents (e.g., zinc dialkyldithiophosphate, ashless phosphorus esters, borate esters)


⚙️ Types of EP Additives

Additive TypeMain ElementApplication Areas
ZDDPZn, P, SEngine oil, light-duty gear oil
Sulfurized olefinsSulfurGear oils, industrial EP fluids
Chlorinated paraffinsChlorineMetalworking fluids (less common now)
Phosphorus estersPhosphorusHydraulic, gear, and ATF applications
Borate compoundsBoronSynthetic fluids, low-ash gear oils

🚜 Common Use Cases

  • Automotive gear oils (GL-4, GL-5)
  • Heavy-duty transmission fluids
  • Industrial gear lubricants
  • Hydraulic fluids in extreme duty
  • Metalworking fluids (cutting, grinding)

Why EP Additives Matter

Extreme Pressure additives are essential for protecting lubricants in high-load, high-friction environments.

Benefits:

  • Prevent wear, scoring, and seizure
  • Extend equipment life
  • Maintain performance under extreme stress
  • Enable compact, high-torque machinery designs

Would you like help selecting the right EP additive type for your gear oil, hydraulic fluid, or metalworking application? I can suggest specific chemistries or treat rates.

The effect of extreme pressure additives on lubricating oils

In the operation of mechanical equipment, lubricating oil plays an indispensable role. It can reduce friction and prevent wear, thereby ensuring the normal operation of mechanical equipment. Extreme pressure additives, as a special chemical substance, play a vital role in lubricating oil.

First, let’s understand the basic concepts of extreme pressure additives and lubricants. Extreme pressure additives are chemicals that can significantly improve the performance of lubricants and are mainly used in industrial and automotive lubricants. Lubricating oil is a mixture of base oil and additives. It has the functions of lubrication, cooling, cleaning, etc., and is suitable for various mechanical equipment.

Extreme pressure additives (EP additives) are chemicals added to lubricating oils to enhance their performance under high-pressure conditions.

Adding extreme pressure additives to lubricating oil can significantly improve the performance of lubricating oil, mainly in the following aspects:

Reduce friction: Extreme pressure additives can penetrate into the friction surface and form a protective film, thereby reducing friction and reducing wear.

Prevent wear and tear: Extreme pressure additives can repair slightly worn surfaces and prevent metal surfaces from wearing due to friction. EP additives form a protective layer on metal surfaces to prevent direct contact and reduce wear. This is particularly important for applications with sliding or rolling contacts such as gears, bearings and sliding mechanisms.

Increase load-bearing capacity: EP additives form a protective film on the metal surface to reduce friction and wear under high-pressure conditions. This allows the lubricant to carry heavier loads without metal-to-metal contact, preventing excessive wear and damage.

What effect do extreme pressure additives have on lubricants?
What effect do extreme pressure additives have on lubricants?

Enhance oil film strength: EP additives improve oil film strength by increasing its viscosity index and reducing its shear rate. This ensures a strong and stable lubricating film even under extreme pressure, preventing metal-to-metal contact and reducing friction, heat generation and wear.

Resistant to Pitting and Scratches: EP additives prevent surface fatigue and damage from pitting and scratches. They form a barrier that prevents the formation of microcracks and other surface defects, thereby extending the service life of the component.

Increase thermal stability: EP additives can improve the stability of lubricating oil at high temperatures. They help prevent oxidation and the formation of sludge and deposits, allowing lubricants to maintain their performance under extreme operating conditions.

Control oil service life: Extreme pressure additives can stabilize the chemical properties of lubricants so that they can maintain their original performance after long-term use.

Extreme pressure additives can be divided into organic extreme pressure additives and inorganic extreme pressure additives according to their chemical properties. Organic extreme pressure additives mainly include compounds of elements such as sulfur, phosphorus, and chlorine, which can chemically react with metal surfaces to form a protective film. Inorganic extreme pressure additives mainly include metal oxides, hydroxides, etc., which are adsorbed on the metal surface through physical effects, thereby reducing friction.

In terms of application, extreme pressure additives are widely used in various mechanical equipment. For example, in the automotive field, extreme pressure additives can be used in engine lubricants to improve engine efficiency and life. In the field of machine tools, extreme pressure additives can be used in key parts such as guide rails and bearings to improve the processing accuracy and production efficiency of machine tools. In addition, extreme pressure additives are also widely used in transmission components such as bearings and gears.

In short, the effect of extreme pressure additives on lubricants is self-evident. By adding extreme pressure additives, the performance of lubricating oil can be significantly improved, friction reduced, wear prevented, and the service life of the oil controlled. Extreme pressure additives play an important role in various fields such as automobiles, machine tools, and bearings. Therefore, when selecting and using lubricating oil, the content of extreme pressure additives and their impact on lubricating oil performance should be fully considered to ensure the normal operation of mechanical equipment and extend its service life.

Leave a Reply

Discover more from Shanghai Minglan Chemical Co.,Ltd.

Subscribe now to keep reading and get access to the full archive.

Continue reading